西亚试剂：Asymmetric photoredox transition-metal catalysis activated

Asymmetric catalysis is seen as one of the most economical strategies to satisfy the growing demand for enantiomerically pure small molecules in the fine chemical and pharmaceutical industries1. And visible light has been recognized as an environmentally friendly and sustainable form of energy for triggering chemical transformations and catalytic chemical processes2, 3, 4, 5. For these reasons, visible-light-driven catalytic asymmetric chemistry is a subject of enormous current interest2, 3, 4, 5. Photoredox catalysis provides the opportunity to generate highly reactive radical ion intermediates with often unusual or unconventional reactivities under surprisingly mild reaction conditions6.

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